Isoelectronic Push-Pull Fluorescent Difluoroborates: Halogen Bonding and Photophysical Properties.

Alex Iglesias-Reguant, Izabela Barańska, Damian Plażuk, Robert Zaleśny, Josep M Luis, Borys Ośmiałowski

Abstract read

In one paragraph

Article in The Journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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0 citing papers in PubMed.

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5 · Who and what money

Authors and funding

6 authors.

Alex Iglesias-ReguantFaculty of Chemistry, Nicolaus Copernicus University, Gagarina Street 7, 87-100 Toruń, Poland.ORCID 0000-0001-7710-8253

Izabela BarańskaFaculty of Chemistry, Nicolaus Copernicus University, Gagarina Street 7, 87-100 Toruń, Poland.

Damian PlażukLaboratory of Molecular Spectroscopy, Department of Organic Chemistry, Faculty of Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Poland.ORCID 0000-0002-2898-6604

Robert ZaleśnyFaculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland.ORCID 0000-0001-8998-3725

Josep M LuisInstitute of Computational Chemistry and Catalysis and Department of Chemistry, University of Girona, Campus de Montilivi, Girona, Catalonia 17003, Spain.ORCID 0000-0002-2880-8680

Borys OśmiałowskiFaculty of Chemistry, Nicolaus Copernicus University, Gagarina Street 7, 87-100 Toruń, Poland.ORCID 0000-0001-9118-9264

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The structural and photophysical properties in the halogen bonding environment were thoroughly studied for a newly synthesized series of fluorescent dyes and their model derivatives. The analysis revealed that the ground-state interactions among both series are likewise. The fluorescent dyes have push-pull topology, and there is a low-lying charge-transfer (CT) excited state in their electronic structure. In order to study the effect of intermolecular interactions on the photophysical parameters of the CT excited state, a palette of solvents was used (C

Identifiers

PMID39931905

DOI10.1021/acs.joc.4c03077

PMCPMC11852195

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