Barrierless Electron Transfer in a Photosynthetic Reaction Center Model.

Tobias Ullrich, Ivana Ramírez-Wierzbicki, Leonardo D Slep, Alejandro Cadranel

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Barrierless Electron Transfer in a Photosynthetic Reaction Center Model.Angewandte Chemie (International ed. in English) · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Tobias UllrichDepartment Chemie und Pharmazie, Physikalische Chemie Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.ORCID https://orcid.org/0009-0003-8250-3356

Ivana Ramírez-WierzbickiUniversidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2 Ciudad Universitaria, C1428EHA, Buenos Aires.ORCID https://orcid.org/0000-0001-8227-7844

Leonardo D SlepUniversidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2 Ciudad Universitaria, C1428EHA, Buenos Aires.ORCID https://orcid.org/0000-0001-6447-2216

Alejandro CadranelDepartment Chemie und Pharmazie, Physikalische Chemie Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.ORCID https://orcid.org/0000-0002-6597-4397

Funding

Consejo Nacional de Investigaciones Científicas y Técnicas PIBAA 2872021010 0877COConsejo Nacional de Investigaciones Científicas y Técnicas PIP 11220200102757COFondo para la Investigación Científica y Tecnológica PICT 2019-02410

6 · The paper itself

Abstract

Vibrational spectroscopy is the ultimate tool to reveal whether any donor-acceptor system is truly delocalized and therefore characterized by a single-welled potential energy surface, or if it is marginally localized with a barrier that defines two minima. Our femtosecond IR absorption investigations on cyanide-bridged mixed valence systems show a broad, intense and downshifted CN vibration signature, revealing, for the first time, an asymmetric, fully delocalized Class III photoinduced mixed valence system.

Indexed as

Class IIICyanide BridgeElectron DelocalizationPhotoinduced Mixed Valence SystemsUltrafast IR

Identifiers

PMID39918123

DOI10.1002/anie.202422633

PMCPMC11914954

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.