Evidence map›Paper›PMID 39915462›Full record

ArticleNature communications2025

Anti-Markovnikov hydroallylation reaction of alkenes via scandium-catalyzed allylic C‒H activation.

Shiyu Wang, Lichao Ning, Tao Mao, Yuqiao Zhou, Maoping Pu, Xiaoming Feng, Shunxi Dong

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Shiyu Wang *Key Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China.
Lichao Ning *Key Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China.
Tao MaoKey Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China.
Yuqiao ZhouKey Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China.
Maoping PuKey Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China.
Xiaoming FengKey Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China.ORCID http://orcid.org/0000-0003-4507-0478
Shunxi DongKey Laboratory of Green Chemistry & Technology Ministry of Education, College of Chemistry Sichuan University, Chengdu, 610064, China. dongs@scu.edu.cn.ORCID http://orcid.org/0000-0002-2687-6006

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22188101National Natural Science Foundation of China (National Science Foundation of China) 22271199National Natural Science Foundation of China (National Science Foundation of China) 92256303Sichuan University (SCU) 2020SCUNL204
6 · The paper itself

Abstract

Compared with rare-earth (RE)…heteroatom interaction, RE…π interaction, frequently used in facilitating regio- and stereoselectivity of olefin polymerizations, is seldomly used to trigger catalytic C - H functionalization. Here, we describe a direct anti-Markovnikov hydroallylation reaction of styrene derivatives with 1-aryl-2-alkyl alkenes and α-alkenes by use of RE…π interaction. This protocol provides a straightforward and atom-efficient route for the synthesis of valuable chain elongated internal alkenes (65 examples, up to 99% yield, > 19:1 E/Z ratio). The reaction proceeds via an allylic Csp

Identifiers

PMID39915462
PMCPMC11802871

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.