Evidence map›Paper›PMID 39900586›Full record

ArticleNature communications2025

Thiophene-fused aromatic belts.

Hiroki Shudo, Philipp Wiesener, Elena Kolodzeiski, Kiichi Mizukami, Daiki Imoto, Harry Mönig, Saeed Amirjalayer, Hirotoshi Sakamoto, Henning Klaasen, Bart Jan Ravoo and 3 more

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Hiroki ShudoDepartment of Chemistry, Graduate School of Science, Nagoya University; Chikusa, Nagoya, Japan.ORCID http://orcid.org/0000-0003-4192-0885
Philipp WiesenerInstitute of Physics, University of Münster, Münster, Germany.
Elena KolodzeiskiTUM School of Natural Sciences, Department of Chemistry, Technical University of Munich, München, Germany.ORCID http://orcid.org/0000-0002-9698-3886
Kiichi MizukamiGraduate School of Engineering, Kyushu University, Fukuoka, Japan.
Daiki ImotoDepartment of Chemistry, Graduate School of Science, Nagoya University; Chikusa, Nagoya, Japan.
Harry MönigInstitute of Physics, University of Münster, Münster, Germany. harry.moenig@uni-muenster.de.ORCID http://orcid.org/0000-0003-2639-9198
Saeed AmirjalayerInterdisciplinary Center for Scientific Computing, Heidelberg University, Heidelberg, Germany. saeed.amirjalayer@iwr.uni-heidelberg.de.ORCID http://orcid.org/0000-0003-0777-5004
Hirotoshi SakamotoInstitute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Kyoto, Japan.ORCID http://orcid.org/0000-0002-0873-1321
Henning KlaasenOrganic Chemistry Institute, University of Münster, Münster, Germany.ORCID http://orcid.org/0000-0002-1930-5969
Bart Jan RavooOrganic Chemistry Institute, University of Münster, Münster, Germany.ORCID http://orcid.org/0000-0003-2202-7485
Nobuo KimizukaGraduate School of Engineering, Kyushu University, Fukuoka, Japan. kimizuka.nobuo.763@m.kyushu-u.ac.jp.
Akiko YagiDepartment of Chemistry, Graduate School of Science, Nagoya University; Chikusa, Nagoya, Japan. yagi.akiko@itbm.nagoya-u.ac.jp.ORCID http://orcid.org/0000-0003-2941-4357
Kenichiro ItamiInstitute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University; Chikusa, Nagoya, Japan. kenichiro.itami@riken.jp.ORCID http://orcid.org/0000-0001-5227-7894

Funding

MEXT | Japan Society for the Promotion of Science (JSPS) 19H05463MEXT | Japan Society for the Promotion of Science (JSPS) 22K21346
6 · The paper itself

Abstract

Aromatic belts, ultrashort carbon nanotubes, and related structures, are emerging molecular entities in the fields of organic electronics and supramolecular chemistry owing to their structural rigidity, fully fused π-conjugation, and well-defined cavity. Synthesis of aromatic belts with embedded thiophene structures, which manifest significant optoelectronic and conductive properties, has not yet been achieved. Herein, we report the synthesis of thiophene-fused aromatic belts (thiophene belts) via one-step sulfur cross-linking reaction of partially fluorinated cycloparaphenylenes. Their structural features, including unidirectional columnar stacking with high dipole moment in crystals, two-dimensional layer assembly on metal surfaces, and photophysical properties, such as long-lifetime phosphorescence, are uncovered. These distinctive features of the thiophene belts should inspire a range of applications such as optoelectronic devices and polar materials.

Identifiers

PMID39900586
PMCPMC11790897

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.