ArticleJournal of the American Chemical Society2025
Bias Dependence of the Transition State of the Hydrogen Evolution Reaction.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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Who cites it
11 citing papers in PubMed.
- Disentangling multistep kinetics by combining electrochemical Arrhenius analysis with micro-kinetic modelling.Faraday discussions · 2026Article
- Compensation effects between the apparent activation energy and pre-exponential factor in simple models of electrocatalytic hydrogen evolution.Faraday discussions · 2026Article
- Confinement-Engineered Ir-IrOAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- The Interplay between Interfacial Solvation and Surface Kinetics Tunes the Selectivity between Hydrogen Evolution and Zinc Electrodeposition.Journal of the American Chemical Society · 2026Article
- Interfacial solvation pre-organizes the transition state of the oxygen evolution reaction.Nature chemistry · 2026Article
- The Remarkable Rise in High-Entropy Catalysts: A New Paradigm for Sustainable Hydrogen Production.Nanomaterials (Basel, Switzerland) · 2026Review
- The role of interfacial excess charge in the reversibility of proton and hydroxide solvation in electrocatalysis and bipolar membranes.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Distinguishing concerted and sequential proton-electron transfer.Nature chemistry · 2026Article
- Pressure and bias dependence of the rate-limiting steps of the oxygen reduction reaction.Nature communications · 2025Article
- Entropy Governs the Structure and Reactivity of Water Dissociation Under Electric Fields.Journal of the American Chemical Society · 2025Article
- Transition state tuning with concentrated electrolytes.Nature chemistry · 2025Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The hydrogen evolution reaction (HER) is one of the most prominent electrocatalytic reactions of green energy transition. However, the kinetics across materials and electrolyte pH and the impact of hydrogen coverage at high current densities remain poorly understood. Here, we study the HER kinetics over a large set of nanoparticle catalysts in industrially relevant acidic and alkaline membrane electrode assemblies that are only operated with pure water humidified gases. We discover distinct kinetic fingerprints between the iron triad (Fe, Ni, Co), coinage (Au, Cu, Ag), and platinum group metals (Ir, Pt, Pd, Rh). Importantly, the applied bias changes not only the activation energy (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.