ArticleAngewandte Chemie (International ed. in English)2025
Validation and Mechanistic Studies of the Headspace Effect in MOF Synthesis.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Transitioning Formamide Solvothermal Syntheses of MOFs to Less Toxic Solvents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Validation and Mechanistic Studies of the Headspace Effect in MOF Synthesis.Angewandte Chemie (International ed. in English) · 2025Article
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3 authors.
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Abstract
The influence of headspace volume and composition on metal-organic framework (MOF) synthesis has been largely overlooked with no mechanisms currently invoking these factors. Herein, we reveal that an increased volume of oxygen in the headspace during the synthesis of zinc carboxylate-based MOFs (MOF-5, MOF-177, and IRMOF-8) as well as UiO-66 and ZJU-28 accelerates crystal formation. Investigation into the underlying mechanism of this phenomenon elucidates the critical roles played by all reagents, and some of their byproducts, in MOF synthesis. These insights are the key to developing more efficient and sustainable synthetic strategies for MOF production.
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