Evidence map›Paper›PMID 39897162›Full record

ArticleSmall science2024

Engineering Supramolecular Hybrid Architectures with Directional Organofluorine Bonds.

Patience A Kotei, Daniel W Paley, Vanessa Oklejas, David W Mittan-Moreau, Elyse A Schriber, Mariya Aleksich, Maggie C Willson, Ichiro Inoue, Shigeki Owada, Kensuke Tono and 12 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Small science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

22 authors.

Patience A KoteiInstitute of Materials Science, University of Connecticut, CT, 06269, USA.
Daniel W PaleyMolecular Biophysics and Integrated Bioimaging Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
Vanessa OklejasMolecular Biophysics and Integrated Bioimaging Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
David W Mittan-MoreauMolecular Biophysics and Integrated Bioimaging Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
Elyse A SchriberInstitute of Materials Science, University of Connecticut, CT, 06269, USA.
Mariya AleksichInstitute of Materials Science, University of Connecticut, CT, 06269, USA.
Maggie C WillsonInstitute of Materials Science, University of Connecticut, CT, 06269, USA.
Ichiro InoueRIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Shigeki OwadaRIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Kensuke TonoRIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Michihiro SugaharaRIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Satomi Inaba-InoueJapan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan.
Andrew AquilaLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Frédéric PoitevinLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Johannes P BlaschkeNational Energy Research Scientific Computing Center, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
Stella LisovaLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Mark S HunterLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Raymond G SierraLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
José A GascónDepartment of Chemistry, University of Connecticut, CT, 06269, USA.
Nicholas K SauterMolecular Biophysics and Integrated Bioimaging Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
Aaron S BrewsterMolecular Biophysics and Integrated Bioimaging Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.
J Nathan HohmanInstitute of Materials Science, University of Connecticut, CT, 06269, USA.

Funding

DIALS: New Computational Methods to Enable Challenging Crystallographic ExperimentsR01GM117126 · NIGMS · UNIVERSITY OF CALIF-LAWRENC BERKELEY LAB · PI SAUTER, NICHOLAS K · 2016 to 2023
$6.1M
High-Repetition Rate X-ray Detector for the Coherent X-ray Imaging Instrument at LCLSS10OD025079 · OD · STANFORD UNIVERSITY · PI BOUTET, SEBASTIEN · 2018 to 2018
$524k
NIGMS NIH HHS R01 GM117126NIH HHS S10 OD025079
6 · The paper itself

Abstract

Understanding how chemical modifications alter the atomic-scale organization of materials is of fundamental importance in materials engineering and the target of considerable efforts in computational prediction. Incorporating covalent and non-covalent interactions in designing crystals while "piggybacking" on the driving force of molecular self-assembly has augmented our efforts to understand the emergence of complex structures using directed synthesis. Here, we prepared microcrystalline powders of the silver 2-, 3-, and 4-fluorobenzenethiolates and resolved their structures by small molecule serial femtosecond X-ray crystallography (smSFX). These three compounds enable us to examine the emergence and role of supramolecular synthons in the crystal structures of three-dimensional metal-organic chalcogenolates (MOChas). The unique divergence in their optoelectronic, morphological, and structural behavior was assessed. The extent of C-H···F interactions and their influence on the structure and the observed trends in the thermal stability of the crystals were quantified through theoretical calculations and thermogravimetric analysis.

Indexed as

C-F bondingCrystal EngineeringMetal-Organic ChalcogenolatessmSFXSupramolecular Synthons

Identifiers

PMID39897162
PMCPMC11784642

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.