ArticleAngewandte Chemie (International ed. in English)2025
Cationic, Iodine(III)-Mediated and Directed Diastereoselective Oxidation of Inert C-H Bonds in Cyclic Hydrocarbons.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Cation Sampling Enables Regiodivergent Distal Functionalization of Ketones.Journal of the American Chemical Society · 2026Article
- Structure-based modeling reveals molecular basis for CYP153A6's novel activity toward toluene derivatives.Scientific reports · 2026Article
- Facile (Z)-Selective Synthesis of β,γ-Unsaturated Ketones by a Silicon-based Olefination Strategy.Angewandte Chemie (International ed. in English) · 2025Article
- Cationic, Iodine(III)-Mediated and Directed Diastereoselective Oxidation of Inert C-H Bonds in Cyclic Hydrocarbons.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Over the past three decades, the functionalization of unactivated C-H bonds has become a workhorse of synthesis. In the field of C-H bond oxygenation, most established methods hinge on single-electron reactivity, encountering challenges pertaining to regio- and/or stereocontrol. Herein, we describe a conceptually distinct strategy relying on the unique features of carbocation chemistry. Our iodine(III)-mediated method achieves the diastereoselective oxygenation of remote C-H bonds at traditionally unreactive sites and enables late-stage functionalization at steroidal frameworks as well as an unusual chirality relay.
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Registered trials
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