Evidence map›Paper›PMID 39890813›Full record

ArticleNature communications2025

Resolving active species during the carbon monoxide oxidation over Pt(111) on the microsecond timescale.

Calley N Eads, Weijia Wang, Ulrike Küst, Julia Prumbs, Robert H Temperton, Mattia Scardamaglia, Joachim Schnadt, Jan Knudsen, Andrey Shavorskiy

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Pt Particles on a Dynamic TiOJournal of the American Chemical Society · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Calley N EadsMAX IV Laboratory, Lund University, Lund, Sweden.
Weijia WangMAX IV Laboratory, Lund University, Lund, Sweden.ORCID http://orcid.org/0000-0003-0602-8162
Ulrike KüstDivision of Synchrotron Radiation Research, Department of Physics, Lund University, Lund, Sweden.ORCID http://orcid.org/0009-0009-0056-3165
Julia PrumbsDivision of Synchrotron Radiation Research, Department of Physics, Lund University, Lund, Sweden.ORCID http://orcid.org/0009-0002-3742-968X
Robert H TempertonMAX IV Laboratory, Lund University, Lund, Sweden.ORCID http://orcid.org/0000-0002-4802-6862
Mattia ScardamagliaMAX IV Laboratory, Lund University, Lund, Sweden.ORCID http://orcid.org/0000-0002-1128-7524
Joachim SchnadtMAX IV Laboratory, Lund University, Lund, Sweden.
Jan KnudsenMAX IV Laboratory, Lund University, Lund, Sweden.
Andrey ShavorskiyMAX IV Laboratory, Lund University, Lund, Sweden. andrey.shavorskiy@maxiv.lu.se.ORCID http://orcid.org/0000-0002-7517-5089

Funding

Svenska Forskningsrådet Formas (Swedish Research Council Formas) 2019-02495Vetenskapsrådet (Swedish Research Council) 2018-07152Vetenskapsrådet (Swedish Research Council) 2022-04363VINNOVA (Swedish Governmental Agency for Innovation Systems) 2018-04969
6 · The paper itself

Abstract

Catalytic studies traditionally rely on steady-state conditions resulting in time-averaged datasets that do not differentiate between active and spectator species. This limitation can cause misinterpretations of catalytic function, as the signal of short-lived intermediates responsible for producing desired reaction products is often masked by more intense spectator species. Time-resolved ambient pressure X-ray photoelectron spectroscopy (tr-APXPS) mitigates this issue by combining microsecond time resolution under reaction conditions. Using tr-APXPS, we investigate the oxidation of CO over Pt(111) by concurrently tracking reaction products, surface intermediates, and catalyst response. Our findings reveal that chemisorbed oxygen, rather than Pt surface oxide, is the main species reacting with CO to form CO

Identifiers

PMID39890813
PMCPMC11785939

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.