Progress in Experimental Methods Using Model Electrodes for the Development of Noble-Metal-Based Oxygen Electrocatalysts in Fuel Cells and Water Electrolyzers.

Hydrogen plays a key role in maximizing the benefits of renewable energy, and the widespread adoption of water electrolyzers and fuel cells, which convert the chemical energy of hydrogen and electrical energy into each other, is strongly desired. Electrocatalysts used in these devices, typically in the form of nanoparticles, are crucial components because they significantly affect cell performance, but their raw materials rely on limited resources. In catalyst research, electrochemical experimental studies using model catalysts, such as single-crystal electrodes, have provided valuable information on reaction and degradation mechanisms, as well as catalyst development strategies aimed at overcoming the trade-off between activity and durability, across spatial scales ranging from the atomic to the nanoscale. Traditionally, these experiments are conducted using well-defined, simple model surfaces like bare single-crystal electrodes in pure systems. However, in recent years, experimental methods using more complex interfaces-while still precisely controlling elemental distribution, microstructure, and modification patterns-have been established. This paper reviews the history of those studies focusing on noble-metal-based electrocatalysts for oxygen reduction reactions and oxygen evolution reactions, which account for the majority of efficiency losses in fuel cells and water electrolyzers, respectively. Furthermore, potential future research themes in experimental studies using model electrodes are identified.