Evidence map›Paper›PMID 39888211›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2025

High-Efficiency Y6 Homojunction Organic Solar Cells Enabled by a Secondary Hole Transport Layer.

Shaun McAnally, Eucalyptus Brooks, Oliver Lindsay, Paul L Burn, Ian R Gentle, Paul E Shaw

Abstract read
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Shaun McAnallyCentre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD, 4072, Australia.ORCID https://orcid.org/0000-0002-8454-1247
Eucalyptus BrooksCentre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD, 4072, Australia.ORCID https://orcid.org/0009-0001-5141-7397
Oliver LindsayCentre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD, 4072, Australia.ORCID https://orcid.org/0009-0003-8128-7110
Paul L BurnCentre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD, 4072, Australia.ORCID https://orcid.org/0000-0003-3405-3517
Ian R GentleCentre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD, 4072, Australia.ORCID https://orcid.org/0000-0001-5573-7868
Paul E ShawCentre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD, 4072, Australia.ORCID https://orcid.org/0000-0002-3326-3670

Funding

Australian Centre for Advanced PhotovoltaicsAustralian Renewable Energy Agency
6 · The paper itself

Abstract

Y6 homojunction solar cells are prepared using the exciton/electron-blocking material poly[9,9-di-n-octylfluorene-alt-N-(4-sec-butylphenyl)diphenylamine] (TFB) as a secondary hole transport layer material in conjunction with PEDOT:PSS. Using this device architecture, a maximum power conversion efficiency (PCE) of 2.57% is achieved, which is the highest reported thus far for a solution-processed small molecule homojunction organic photovoltaic (OPV) device. The devices display an unexpectedly low thickness dependence, with the average PCE only decreasing by ≈17% when the Y6 active layer thickness is increased from 80 to 300 nm. Time-resolved photoluminescence measurements show that the TFB does not contribute to charge generation through photoinduced hole or electron transfer. However, transient absorption spectroscopy on thin films of neat Y6 and a 1:1 blend of Y6:TFB shows that the TFB enhances the formation of the long-lived Y6 intermolecular charge-transfer state in the blend film. It is found that careful selection of the electron transport layer (ETL) is required to avoid unintended charge generation at the interface with Y6 so as to ensure that the device is a true homojunction. The improved efficiency of this architecture is attributed to the electron-blocking and hole-extraction effects of the TFB layer.

Indexed as

hole transport layerhomojunctionnon‐fullerene acceptororganic solar cell

Identifiers

PMID39888211
PMCPMC11855233

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.