ArticleAngewandte Chemie (International ed. in English)2025
A Bis-Perylene Diimide Macrocycle Chiroptical Switch.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Chiral Alanine Functionalized Perylene Diimides: Supramolecular Self-Assembly and Optical Properties.Molecules (Basel, Switzerland) · 2026Article
- Delicate molecular design, self-assembly and functional applications of chiral cyclophanes.Chemical science · 2026Review
- Conformational switching modulates excited-state pathways in a cofacial perylene dimer.Chemical science · 2026Article
- Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle.Angewandte Chemie (International ed. in English) · 2026Article
- Dynamics and Conformational Stability of Chiral Bay-Phenolate-Substituted Twisted Octaazaperopyrenedioxides (OAPPDOs).Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Chirally locked and dynamic bis-perylene diimide macrocycles with multiple sources of chirality.Communications chemistry · 2026Article
- Controlling optoelectronic properties and aggregation of planar dipoles through symmetry-preserving modifications.Chemical science · 2026Article
- Synergistic 3D π-π networks enforce persistent foldamer configuration with tunable full-color circularly polarized luminescence.Communications chemistry · 2025Article
- Circular Dichroism and Multiphoton Circularly Polarized Luminescence Switching Using a Bis-perylene Diimide Macrocycle.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Core-Twisted, Cationic Perylene Diimides; Homochiral Dimerization and Chiroptical Anion Sensing.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Chiral ring-in-ring complexes with torsion-induced circularly polarized luminescence.Chemical science · 2025Article
- A Bis-Perylene Diimide Macrocycle Chiroptical Switch.Angewandte Chemie (International ed. in English) · 2025Article
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5 authors.
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Abstract
Helical assemblies of organic dyes are ubiquitous chiral organic materials, with valuable properties including chiroptical switching due to the dynamic nature of supramolecular chirality. Herein, we report a novel chiral bis-perylene diimide macrocycle, which acts as a discrete molecular model for a chiral supramolecular assembly. Point chirality is installed through amino acid-derived imide groups which, upon macrocyclization, is translated into helical chirality in the perylene diimide dimer. In solution, the macrocycle's chiroptical properties are switchable, with both the sign (+/-) and amplitude (on/off) of the signal tuned using solvent and molecular recognition stimuli respectively. The chiral structure-property relationships identified from this macrocycle are important for the design of high fidelity supramolecular chiroptical switches.
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