Evidence map›Paper›PMID 39887652›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Inversion of Circularly Polarized Luminescence in the Left-Handed Chitosan-Templated Co-assemblies.

Yu An, Zhaocun Shen, Fang Zhang, Qiuya Yang, Zihan Han, Mingjie Wang, Hongze Ma, Linjie Yu, Wei Yuan, Kunyan Sui

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Yu AnState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Zhaocun ShenState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Fang ZhangState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Qiuya YangState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Zihan HanState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Mingjie WangState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Hongze MaState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Linjie YuState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.
Wei YuanSchool of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.
Kunyan SuiState Key Laboratory of Bio-Fibers and Eco-textiles, College of Materials Science and Engineering, Key Laboratory of Shandong Provincial Universities for Advanced Fibers and Composites, Qingdao University, 308 Ningxia Road, Qingdao, 266071, P. R. China.

Funding

China Postdoctoral Science Foundation 2021M701809China Postdoctoral Science Foundation 2023T160347National Natural Science Foundation of China 22202113Natural Science Foundation of Shandong Province 2022HWYQ-083Natural Science Foundation of Shandong Province ZR2021QB006Taishan Scholar Foundation of Shandong Province tsqnz20221136Taishan Scholar Foundation of Shandong Province tstp20231226
6 · The paper itself

Abstract

Circularly polarized luminescence (CPL) materials are attractive due to their unique applications in fields such as 3D displays, information encryption, and chiroptical switches. Natural biomolecules-based CPL materials are gaining plenty of attention due to their chiral diversity and sustainability. However, it is still challenging to construct CPL materials with opposite CPL signs from a single natural biomolecule due to its inherent chirality. Here, chiral assemblies with opposite CPL signs using chitosan oligosaccharide (COS) and achiral luminescent dyes are successfully prepared. It is found that COS can serve as a chiral template to induce the ordered assembly of the dyes along the polymer chain through electrostatic attraction interaction. It is demonstrated experimentally that the structural planarity of the dye molecules is crucial for the formation of chiral co-assemblies. Interestingly, the left-handed COS-templated co-assemblies can emit CPL with opposite handedness, which is controlled by the helicity degree of the co-assemblies. This study not only deepens the understanding of the complex assembly of natural biomacromolecules but also provides new insights into the design and construction of CPL materials.

Indexed as

chiral assemblychitosancircularly polarized luminescenceJ‐aggregates

Identifiers

PMID39887652
PMCPMC11948070

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.