ArticleJournal of the American Chemical Society2025
Transient Triplet Metallopnictinidenes M-Pn (M = Pd
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- N‑Heterocyclic Carbene-Supported Cuprous Phosphaethynolates and Their P-atom Transfer.ACS omega · 2026Article
- Structure, Stability, Spectroscopy and Chemical Bonding Analyses on the Novel XJournal of computational chemistry · 2026Article
- Metallaphosphinidene Coupling with a Phosphorus Ylide to Form a Phosphavinyl [P═CHJournal of the American Chemical Society · 2026Article
- A Mixed-Valent and High-Spin Vanadium Phosphide.Journal of the American Chemical Society · 2026Article
- Gold(III)-Substituted Carbenes.Journal of the American Chemical Society · 2026Article
- A Consistent Approach to One Coordinate Pnictide Moieties M≡PnAngewandte Chemie (International ed. in English) · 2026Article
- Isolable f-element diphosphene complexes by phosphinidene group transfer and coupling at uranium.Nature communications · 2025Article
- Historical and Recent Developments in the Chemistry of Cyanate Congeners.Inorganic chemistry · 2025Review
- Reversible Decarbonylation of a Metal Phosphaketene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Review
- P-P CouplingJournal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
14 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nitrenes (R-N) have been subject to a large body of experimental and theoretical studies. The fundamental reactivity of this important class of transient intermediates has been attributed to their electronic structures, particularly the accessibility of triplet vs singlet states. In contrast, electronic structure trends along the heavier pnictinidene analogues (R-Pn; Pn = P-Bi) are much less systematically explored. We here report the synthesis of a series of metallodipnictenes, {M-Pn═Pn-M} (M = Pd
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Registered trials
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