ArticleJournal of the American Chemical Society2025
P-P Coupling
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
8 citing papers in PubMed.
- N‑Heterocyclic Carbene-Supported Cuprous Phosphaethynolates and Their P-atom Transfer.ACS omega · 2026Article
- Metallaphosphinidene Coupling with a Phosphorus Ylide to Form a Phosphavinyl [P═CHJournal of the American Chemical Society · 2026Article
- A Mixed-Valent and High-Spin Vanadium Phosphide.Journal of the American Chemical Society · 2026Article
- Gold(III)-Substituted Carbenes.Journal of the American Chemical Society · 2026Article
- Diverging Reactivity in Anilidophosphine Supported Group III Complexes.Chemistry, an Asian journal · 2025Article
- Reversible Decarbonylation of a Metal Phosphaketene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Review
- Transient Triplet Metallopnictinidenes M-Pn (M = PdJournal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Terminal metal-phosphorus (M-P) complexes are of significant contemporary interest as potential platforms for P-atom transfer (PAT) chemistry. Decarbonylation of metal-phosphaethynolate (M-PCO) complexes has emerged as a general synthetic approach to terminal M-P complexes. M-P complexes that are stabilized by strong M-P multiple bonds are kinetically persistent and isolable. In the absence of strong M-P stabilization, the formation of diphosphorus-bridged complexes (i.e., M-P-P-M species) is often interpreted as evidence for the intermediacy of reactive, unobserved M-P species. Here, we demonstrate that while diphosphorus complexes can arise from reactive M-P species, P-P coupling can also proceed directly from M-PCO species without the intermediacy of M-P complexes. Photochemical decarbonylations of a pincer-supported Ni (II)-PCO complex at 77 K afford a spectroscopically observed terminal Ni-P complex, which is best described as a triplet, Ni(II)-metallophosphinidene with two unpaired electrons localized on the atomic phosphorus ligand. Thermal annealing of this transient Ni-P complex results in rapid dimerization to afford the corresponding P
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.