Polyurethane-grafted graphene oxide from repurposed foam mattress waste.

Polyurethanes (PU) make up a large portion of commodity plastics appearing in applications including insulation, footwear, and memory foam mattresses. Unfortunately, as thermoset polymers, polyurethanes lack a clear path for recycling and repurposing, creating a sustainability issue. Herein, using dynamic depolymerization, we demonstrate a simple one-pot synthesis for preparation of an upcycled polyurethane grafted graphene material (PU-GO). Through this dynamic depolymerization using green conditions, PU-GO nanofillers with tunable PU to GO ratios were synthesized. Chemical analysis revealed that the polyurethane graphenic materials primarily contained the polycarbamate hard-segment of polyurethane while the soft polyol component was removed in washes. PU-GOs were incorporated into bulk polyurethane foam to create composites as a filler at 0.25, 0.5, 1.0, and 2.0 weight percent filler and the thermal and mechanical properties of the resulting foams were analyzed. All PU-GO fillers were shown to improve thermal insulation up to a filler content of 0.5%, with all but 2 of the fillers demonstrating improvements up to 2% of filler content. The greatest decrease in thermal conductivity was 38.5% compared to neat PU foam, observed with the composites containing 0.5% of PU