Evidence map›Paper›PMID 39871766›Full record

ReviewAdvanced materials (Deerfield Beach, Fla.)2025

Adsorption and Separation by Flexible MOFs.

Irena Senkovska, Volodymyr Bon, Antonia Mosberger, Yutong Wang, Stefan Kaskel

Abstract readReview
In one paragraph

Review in Advanced materials (Deerfield Beach, Fla.), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.

0numbers the graph read from it
0cells of the map it votes in
25citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

25 citing papers in PubMed.

  1. Article
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  19. Article
  20. MOF-Derived CoMicromachines · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Irena SenkovskaChair of Inorganic Chemistry I, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany.ORCID https://orcid.org/0000-0001-7052-1029
Volodymyr BonChair of Inorganic Chemistry I, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany.
Antonia MosbergerChair of Inorganic Chemistry I, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany.
Yutong WangChair of Inorganic Chemistry I, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany.
Stefan KaskelChair of Inorganic Chemistry I, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany.

Funding

Alexander von Humboldt FoundationBMBF 05K22OD1BMBF 05K22OD2German Research Foundation 448809307
6 · The paper itself

Abstract

Flexible metal-organic frameworks (MOFs) offer unique opportunities due to their dynamic structural adaptability. This review explores the impact of flexibility on gas adsorption, highlighting key concepts for gas storage and separation. Specific examples demonstrate the principal effectiveness of flexible frameworks in enhancing gas uptake and working capacity. Additionally, mixed gas adsorption and separation of mixtures are reviewed, showcasing their potential in selective gas separation. The review also discusses the critical role of the single gas isotherms analysis and adsorption conditions in designing separation experiments. Advanced combined characterization techniques are crucial for understanding the behavior of flexible MOFs, including monitoring of phase transitions, framework-guest and guest-guest interactions. Key challenges in the practical application of flexible adsorbents are addressed, such as the kinetics of switching, volume change, and potential crystal damage during phase transitions. Furthermore, the effects of additives and shaping on flexibility and the "slipping off effect" are discussed. Finally, the benefits of phase transitions beyond improved working capacity and selectivity are outlined, with a particular focus on the advantages of intrinsic thermal management. This review highlights the potential and challenges of using flexible MOFs in gas storage and separation technologies, offering insights for future research and application.

Indexed as

adsorption selectivitybreathingflexible metal–organic frameworksgas separationgas storagegate openingsoft porous crystals

Identifiers

PMID39871766
PMCPMC12747485

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.