ArticleJournal of the American Chemical Society2025
Enhancing Electron Donor-Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal-Organic Framework.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
4 citing papers in PubMed.
- Association-gated multiphoton activation of inert haloarenes via sequential electron donor-acceptor assembly.Nature communications · 2026Article
- Topological engineering of covalent organic frameworks enhances photoactivation of electron donor-acceptor complexes via conformational locking.National science review · 2026Article
- Construction of Heteroleptic Copper Complexes in Perylene Diimide-Based COFs for Heterogeneous Metallaphotoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Air-Insensitive Sulfonylation Enabled by a MOF-Supported Nickel Photocatalyst.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
Corrections and comments
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electron donor-acceptor complexes are commonly employed to facilitate photoinduced radical-mediated organic reactions. However, achieving these photochemical processes with catalytic amounts of donors or acceptors can be challenging, especially when aiming to reduce catalyst loadings. Herein, we have unveiled a framework-based heterogenization approach that significantly enhances the photoredox activity of perylene diimide species in radical addition reactions with alkyl silicates by promoting faster and more efficient electron donor-acceptor complex formation. Besides offering broad substrate scope in alkene hydroalkylation, the newly developed heterogeneous photocatalysis substantially improves the catalyst turnover numbers in comparison to previous homogeneous photocatalytic systems and demonstrates outstanding catalyst recyclability. These research findings pave the way for the advancement of various efficient and practical organic transformations using framework-supported organocatalysts.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.