Evidence map›Paper›PMID 39861204›Full record

ArticlePolymers2025

Development of Bio-Based and Recyclable Epoxy Adhesives by Modification with Thermoplastic Polymers.

Riccardo Miranda, Marco Luciano, Vincenzo Fiore, Antonino Valenza

Abstract read
In one paragraph

Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Riccardo MirandaDepartment of Engineering, University of Palermo, Viale delle Scienze, Edificio 6, 90128 Palermo, Italy.ORCID 0000-0002-5055-5173
Marco LucianoDepartment of Engineering, University of Palermo, Viale delle Scienze, Edificio 6, 90128 Palermo, Italy.
Vincenzo FioreDepartment of Engineering, University of Palermo, Viale delle Scienze, Edificio 6, 90128 Palermo, Italy.ORCID 0000-0002-9794-1362
Antonino ValenzaDepartment of Engineering, University of Palermo, Viale delle Scienze, Edificio 6, 90128 Palermo, Italy.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This paper deals with the design of novel epoxy adhesives by incorporating thermoplastic polymers such as polyetherimide (PEI) and poly(ε-caprolactone) (PCL) into a bio-based and recyclable epoxy resin, known as Polar Bear. The adhesives were characterized by their mechanical (quasi-static and dynamic) and rheological properties, thermal stability, and adhesion properties in single-lap joints tested at three different temperatures (i.e., -55 °C, 23 °C, 80 °C). The experimental results indicated that low PEI content substantially improved the mechanical performance and toughness of the adhesive, while preserving good processability. Nonetheless, exceeding 3% weight percentage adversely affected the adhesives' mechanical resistance and workability. Conversely, while PCL addition enhanced the adhesives' viscosity, it also decreased mechanical performance. However, its eco-friendliness offers potential for sustainable adhesive applications. It is worth noting that regardless of temperature, the modified adhesives consistently outperformed the commercial epoxy adhesive (DP-460), used as reference, in single-lap shear joint tests. Additionally, both PEI- and PCL-modified epoxy adhesives have demonstrated recyclability through a simple acid-based process, enabling joint disassembly and recycling of the adhesive into a thermoplastic polymer. Overall, the modified adhesives represent a promising eco-friendly, high-performance alternative for structural applications, aligning with sustainable and circular practices.

Indexed as

disassemblingepoxy adhesivepolyetherimide (PEI)poly-ε-caprolactone (PCL)recyclingsingle-lap joint

Identifiers

PMID39861204
PMCPMC11768196

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.