ArticleMolecules (Basel, Switzerland)2025
Development of Homogeneous Carboxylation of Phenolates via Kolbe-Schmitt Reaction.
Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- A Para-Selective Kolbe-Schmitt Reaction.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of Hydroxyaromatic Carboxylic Acids via Homogeneous Kolbe-Schmitt Carboxylation of Phenoxides.Molecules (Basel, Switzerland) · 2026Article
- Exploring the Potentials of Membrane Gas Separation for CO Concentration After Plasma Catalytic COMembranes · 2025Article
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Authors and funding
7 authors.
Funding
Abstract
In this study, the homogeneous carboxylation of potassium, sodium, and lithium phenolates in DMSO solution at 100 °C by the Kolbe-Schmitt reaction was investigated. The impact of water, phenolate concentration, and cation nature on the yield of products and reaction selectivity was demonstrated. Based on the patterns observed, it was concluded that a complex cluster mechanism governs the carboxylation reaction in the solution. The use of a homogeneous reaction medium allowed for convenient testing of various additives to assess their impact on the reaction. Basic additives such as sodium salts of mesitol,
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Registered trials
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