ArticleJournal of the American Chemical Society2025
Making Mo(0) a Competitive Alternative to Ir(III) in Phosphors and Photocatalysts.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
7 citing papers in PubMed.
- Controlled Dimerization of Rhodium(I) Isocyanides Enables Photophysical Properties Beyond Mononuclear Complexes.JACS Au · 2026Article
- Controlling Redox and Photophysical Properties of First-Row Transition Metal Complexes via Ligand Perhalogenation.Inorganic chemistry · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
- Photocatalyzed Ring Expansion of α-Ketosulfonylaziridines: Ready Access to δ-Sultams.Angewandte Chemie (International ed. in English) · 2026Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- A Near-Infrared-II Luminescent and Photoactive Vanadium(II) Complex with a 760 ns Excited State Lifetime.Journal of the American Chemical Society · 2025Article
- Molecular Design Principles for Photoactive Transition Metal Complexes: A Guide for "Photo-Motivated" Chemists.Journal of the American Chemical Society · 2025Review
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Iridium is used in commercial light-emitting devices and in photocatalysis but is among the rarest stable chemical elements. Therefore, replacing iridium(III) in photoactive molecular complexes with abundant metals is of great interest. First-row transition metals generally tend to yield poorer luminescence behavior, and it remains difficult to obtain excited states with redox properties that exceed those of noble-metal-based photocatalysts. Here, we overcome these challenges with a nonprecious second-row transition metal. Tailored coordination spheres for molybdenum(0) lead to photoluminescence quantum yields that rival those of iridium(III) complexes and photochemical reduction reactions not normally achievable with iridium(III) become possible. These developments open new perspectives for replacing noble metals in lighting applications with Earth-abundant metals and for advancing metal-based photocatalysis beyond current limits.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.