ArticleNature physics2025
Electronic dynamics created at conical intersections and its dephasing in aqueous solution.
Article in Nature physics, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Ultrafast Spectroscopy with anACS physical chemistry Au · 2026Article
- Unifying Decoherence and Phase Evolution in Mixed Quantum-Classical Dynamics through Exact Factorization.The journal of physical chemistry letters · 2026Article
- Signatures of Antisymmetric Vibrations in the Ultrafast Dynamics of Quadrupolar Dyes.The journal of physical chemistry letters · 2026Article
- Capturing coherent pseudorotation through conical intersection in photoionized benzene.Nature communications · 2025Article
- Creating a designer cyanobacterial ecosystem for the sustainable production of biomass rich in sun-protecting compounds: mycosporine-like amino acids and scytonemin.Archives of microbiology · 2025Review
- An Improved Virtual Orbital Driven Similarity Renormalization Group Approach for Core-Ionized and Core-Excited States.Journal of chemical theory and computation · 2025Article
- Snooping on the conical intersection.Nature reviews. Chemistry · 2025Article
- Ultrafast spectroscopy of liquids using extreme-ultraviolet to soft-X-ray pulses.Nature reviews. Chemistry · 2025Review
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11 authors.
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Abstract
A dynamical rearrangement in the electronic structure of a molecule can be driven by different phenomena, including nuclear motion, electronic coherence or electron correlation. Recording such electronic dynamics and identifying its fate in an aqueous solution has remained a challenge. Here, we reveal the electronic dynamics induced by electronic relaxation through conical intersections in both isolated and solvated pyrazine molecules using X-ray spectroscopy. We show that the ensuing created dynamics corresponds to a cyclic rearrangement of the electronic structure around the aromatic ring. Furthermore, we found that such electronic dynamics were entirely suppressed when pyrazine was dissolved in water. Our observations confirm that conical intersections can create electronic dynamics that are not directly excited by the pump pulse and that aqueous solvation can dephase them in less than 40 fs. These results have implications for the investigation of electronic dynamics created during light-induced molecular dynamics and shed light on their susceptibility to aqueous solvation.
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