ArticleACS applied materials & interfaces2025
Advanced Nodular Thin Dense Chromium Coating: Superior Corrosion Resistance.
Article in ACS applied materials & interfaces, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Chromium-based functional coatings (CFCs) are widely recognized for their outstanding wear and corrosion resistance across diverse industrial sectors. However, despite advancements in deposition techniques and microstructural enhancements, many contemporary CFCs remain vulnerable to degradation in highly corrosive environments. For the first time, this research delivers a thorough characterization of the corrosion resistance of advanced CFCs, focusing on the performance of a 5 μm thin dense chromium (TDC) coating. These TDCs exhibit a distinctive, uniform nodular microstructure, characterized by approximately 3.6 μm nodules composed of defect-free near-nanocrystalline grains (227 ± 75 nm) plus enhanced electrochemical nobility. This structure promotes the rapid formation of a stable, dense bilayer oxide, resulting in a remarkably low corrosion susceptibility, effectively impeding both charge transfer and mass transport, particularly the diffusion of Cl
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