Evidence map›Paper›PMID 39840576›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO

Adrien Smith, Philipp Gotico, Régis Guillot, Stéphane Le Gac, Winfried Leibl, Ally Aukauloo, Bernard Boitrel, Marie Sircoglou, Zakaria Halime

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Directional Second Sphere Effect on COAngewandte Chemie (International ed. in English) · 2026
    Article
  2. Review
  3. Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Adrien SmithUniversité Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Orsay, 91400, France.ORCID https://orcid.org/0000-0002-6207-4430
Philipp GoticoInstitute for Integrative Biology of the Cell, CEA, CNRS, Université Paris-Saclay, Gif-sur-Yvette, 91191, France.ORCID https://orcid.org/0000-0003-2926-6016
Régis GuillotUniversité Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Orsay, 91400, France.ORCID https://orcid.org/0000-0002-9003-0670
Stéphane Le GacUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, Rennes, 35000, France.ORCID https://orcid.org/0000-0002-9897-3171
Winfried LeiblInstitute for Integrative Biology of the Cell, CEA, CNRS, Université Paris-Saclay, Gif-sur-Yvette, 91191, France.ORCID https://orcid.org/0000-0002-2313-6643
Ally AukaulooUniversité Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Orsay, 91400, France.ORCID https://orcid.org/0000-0002-5480-1642
Bernard BoitrelUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, Rennes, 35000, France.ORCID https://orcid.org/0000-0002-3822-8831
Marie SircoglouUniversité Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Orsay, 91400, France.ORCID https://orcid.org/0000-0002-6303-5222
Zakaria HalimeUniversité Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Orsay, 91400, France.ORCID https://orcid.org/0000-0003-3080-9727

Funding

Agence Nationale de la Recherche ANR-19-CE05-0020-02Grand Équipement National De Calcul Intensif A0150810977
6 · The paper itself

Abstract

To efficiently capture, activate, and transform small molecules, metalloenzymes have evolved to integrate a well-organized pocket around the active metal center. Within this cavity, second coordination sphere functionalities are precisely positioned to optimize the rate, selectivity, and energy cost of catalytic reactions. Inspired by this strategy, an artificial distal pocket defined by a preorganized 3D strap is introduced on an iron-porphyrin catalyst (sc-Fe) for the CO

Indexed as

artificial distal pocketbiomimeticcarbon dioxideelectrocatalysishydrogen bonding

Identifiers

PMID39840576
PMCPMC11923859

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.