ReviewChemical Society reviews2025
Chiral-at-metal catalysts: history, terminology, design, synthesis, and applications.
Review in Chemical Society reviews, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
9 citing papers in PubMed.
- Solvent-Guided Chiral Assemblies and Chemical Doping of OEG-Functionalized Conjugated Polymers.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Imidazol-2-ylidene-Based NCCN Ligands for Chiral-at-Iron Catalysis.Organometallics · 2026Article
- Control over stereogenic centres beyond tetracoordination.Chemical science · 2026Review
- Sustainable and Scalable Flow Photochemical Conversions Using a Labile Ligand-Assembled Iron Complex.JACS Au · 2026Article
- An Achiral Tetradentate Cis-α-Coordinating NCCN Ligand Gives Rise to a Configurationally Stable Chiral-at-Iron Complex for Enantioselective Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Catalytic Enantioselective Methods for Synthesis of 1,2-Amino Tertiary Alcohols and Their Analogues.Chemical reviews · 2025Review
- Privileged Chiral Photocatalysts.Angewandte Chemie (International ed. in English) · 2025Review
- Cobalt catalyst with exclusive metal-centered chirality for asymmetric photocatalysis.Nature communications · 2025Article
- Chiral-at-Tungsten Dioxo Complexes─A Computational Study on Inhibiting Racemization.Inorganic chemistry · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
For decades, advances in chiral transition metal catalysis have been closely tied to the development of customized chiral ligands. Recently, however, an alternative approach to this traditional metal-plus-chiral-ligand method has emerged. In this new strategy, chiral transition metal catalysts are composed entirely of achiral ligands, with the overall chirality originating exclusively from a stereogenic metal center. This "chiral-at-metal" approach offers the benefit of structural simplicity. More importantly, by removing the need for chiral elements within the ligand framework, it opens up new possibilities for designing innovative catalyst architectures with unique properties. As a result, chiral-at-metal catalysis is becoming an increasingly important area of research. This review offers a comprehensive overview and detailed insights into asymmetric chiral-at-metal catalysis, encouraging scientists to explore new avenues in asymmetric transition metal catalysis and driving innovation in both fundamental and applied research.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.