ArticleNature materials2025
Revitalizing interphase in all-solid-state Li metal batteries by electrophile reduction.
Article in Nature materials, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 12 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
12 citing papers in PubMed.
- A Fixed-Charge Interphase Synchronizes Ion Transport to Suppress Space-Charge-Driven Inefficiency Under Nanoliter Confinement.Angewandte Chemie (International ed. in English) · 2026Article
- Constructing zero-external-pressure high-performance sulfide all-solid-state pouch cells via asymmetric interfacial electrophilicity.Science advances · 2026Article
- Size-Dependent Trade-off between Sulfur Catalysis and Sulfide Electrolyte Decomposition for Room-Temperature Ultrahigh-Rate All-Solid-State Li-S Batteries.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Ultrafast Reactive Laser Sintering of Highly Conductive Garnet-Type LLZTO Solid Electrolytes.ACS applied materials & interfaces · 2026Article
- Bulk-to-interface fluorination for stable and low-pressure all-solid-state lithium metal batteries.Nature communications · 2026Article
- A Scalable BaTiOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Space charge regulation for ultra-stable all-solid-state lithium batteries by engineering of argyrodite electrolyte.National science review · 2026Article
- Advanced Thermal Interface Materials: Insights into Low-Temperature Sintering and High Thermal Conductivity of MgO.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Enabling Anode-Less Lithium Batteries via Sacrificial Salts: An In-Depth Feasibility Analysis.ACS applied materials & interfaces · 2025Article
- Why Will Polymers Win the Race for Solid-State Batteries?Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Interlayer Design for Halide Electrolytes in All-Solid-State Lithium Metal Batteries.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Facilitating uniform lithium-ion transport via polymer-assisted formation of unique interfaces to achieve a stable 4.7 V Li metal battery.National science review · 2025Article
Corrections and comments
- Erratum issued
Authors and funding
11 authors.
Funding
Abstract
All-solid-state lithium metal batteries promise high levels of safety and energy density, but their practical realization is limited by low Li reversibility, limited cell loading and demand for high-temperature and high-pressure operation, stemming from solid-state electrolyte (SSE) low-voltage reduction and high-voltage decomposition, and from lithium dendrite growth. Here we concurrently address these challenges by reporting that a family of reductive electrophiles gain electrons and cations from metal-nucleophile materials (here a Li sulfide SSE) upon contact to undergo electrochemical reduction and form interphase layers (named solid reductive-electrophile interphase) on material surfaces. The solid reductive-electrophile interphase is electron blocking and lithiophobic, prevents SSE reduction, suppresses Li dendrites and supports high-voltage cathodes. Consequently, a reductive-electrophile-treated SSE exhibits high critical capacity and Li reversibility at the anode, and enables Li(1% Mg)/SSE/LiNi
Identifiers
39833391What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.