ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025
Phosphorus-Nitrogen Heterocycles Derived from Chelating N-Donor Ligands: Historical Advances, Recent Highlights, and Outlook.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- A Crystalline Bismuth(II) Radical Anion: Synthesis, Characterization, and Reactivity.Angewandte Chemie (International ed. in English) · 2025Article
- Phosphorus-Nitrogen Heterocycles Derived from Chelating N-Donor Ligands: Historical Advances, Recent Highlights, and Outlook.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
The exploration of phosphorus-nitrogen heterocycles derived from chelating N-donor ligands is an area of research that has lagged behind the development of similar heterocycles based on other main group elements, most notably boron. The fact that phosphorus and nitrogen are both group 15 elements and that their compounds are most commonly viewed as Lewis bases likely contributes to this observation. However, through judicious ligand design and creative use of phosphorus sources that render phosphorus as Lewis acidic and/or electron poor, a variety of heterocyclic architectures are possible. In this article, we highlight selected examples of phosphorus adducts of bidentate, tridentate, and tetradentate N-donor ligands that have shown utility as functional molecular materials, in small molecule activation and catalysis, and as therapeutics and diagnostics in chemical biology. Finally, we look forward to the future of this emerging area and provide commentary on the unique opportunities available to researchers working within the field of phosphorus-nitrogen heterocycle chemistry.
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Registered trials
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