Evidence map›Paper›PMID 39817800›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Upgrade of Weak σ-Hole Bond Donors via Cr(CO)

Arun Dhaka, Roberta Beccaria, Andrea Pizzi, Elena Yu Tupikina, Vadim Yu Kukushkin, Giuseppe Resnati

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Tuning probe permeabilityChemical science · 2025
    Article
  3. Taxonomy of Chemical Bondings: Opportunities and Challenges.Angewandte Chemie (International ed. in English) · 2025
    Article
  4. Upgrade of Weak σ-Hole Bond Donors via Cr(CO)Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Arun DhakaNFMLab, Dept. Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131, Milano, Italy.ORCID https://orcid.org/0000-0003-4130-5364
Roberta BeccariaNFMLab, Dept. Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131, Milano, Italy.ORCID https://orcid.org/0009-0009-6574-3271
Andrea PizziNFMLab, Dept. Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131, Milano, Italy.ORCID https://orcid.org/0000-0002-4180-9151
Elena Yu TupikinaInstitute of Chemistry, Saint Petersburg State University, Universitetskaya Emb 7/9, 199034, Saint Petersburg, Russian Federation.ORCID https://orcid.org/0000-0002-0998-8348
Vadim Yu KukushkinInstitute of Chemistry, Saint Petersburg State University, Universitetskaya Emb 7/9, 199034, Saint Petersburg, Russian Federation.ORCID https://orcid.org/0000-0002-2253-085X
Giuseppe ResnatiNFMLab, Dept. Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131, Milano, Italy.ORCID https://orcid.org/0000-0002-0797-9296

Funding

Ministero dell'Università e della Ricerca, PRIN-2020, project NICE no. 2020Y2CZJ2Ministero dell'Università e della Ricerca, PRIN-2022, project FLIPPER no. 202224KAX8
6 · The paper itself

Abstract

Molecular recognition mediated by σ-hole interactions is enhanced as the electrostatic potential at the σ-hole becomes increasingly positive. Traditional methods to strengthen σ-hole donor ability of atoms such as halogens often involve covalent modifications, such as, introducing electron-withdrawing substituents (neutral or positively charged) or electrochemical oxidation. Metal coordination, a relatively underexplored approach, offers a promising alternative. In this study, η

Indexed as

ActivationChlorineComplexationHalogen bondσ-hole

Identifiers

PMID39817800
PMCPMC11855244

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.