ArticleThe journal of physical chemistry. B2025
Ion-Ion Association in Bulk Mixed Electrolytes Using Global and Local Electroneutrality Constraints.
Article in The journal of physical chemistry. B, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
3 citing papers in PubMed.
- Fractional Ion Contributions to Mixed Electrolyte Ion Atmospheres from Experimental Thermodynamic Data.The journal of physical chemistry. B · 2026Article
- Quantifying ion-ion association in mixed electrolyte systems using bulk thermodynamic experimental data.The Journal of chemical physics · 2026Article
- Ion Adsorption at Surfaces from Local and Global Electroneutrality Constraints.Langmuir : the ACS journal of surfaces and colloids · 2026Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Ion atmospheres play a critical role in modulating the interactions between charged components in solutions. However, a detailed description of the nature of ion atmospheres remains elusive. Here, we use Kirkwood-Buff theory, an exact theory of solution mixtures, together with a series of local and bulk electroneutrality constraints to provide relationships between all the net ion-ion distributions in bulk electrolyte mixtures. The validity of the underlying relationships is then confirmed using classical explicit solvent molecular simulations of a range of electrolyte mixtures. Further analysis indicates the ion distributions can be separated into two contributions, one resulting in charge neutralization, for which each ion contributes in proportion to its ionic strength, and the other accounting for all the solution thermodynamics. The relationships hold for atomic and molecular ions of any size and valency regardless of ionic strength, temperature, or pressure, in any solvent system.
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Registered trials
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