Evidence map›Paper›PMID 39811000›Full record

ReviewChemical science2025

Recent advances and perspectives in synthetic applications of silylboronates as silyl radical precursors.

Zhihua Cai, Qing-Qing Bu, Xi-Yu Wang, Shengchao Yang, Jian Zhou, Jin-Sheng Yu

Abstract readReview
PubMed Full text at PMC Publisher
In one paragraph

Review in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Review
  2. Article
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Zhihua CaiSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University Shihezi Xinjiang 832003 P. R. China shengchao.yang@shzu.edu.cn.ORCID https://orcid.org/0000-0002-4861-7056
Qing-Qing BuSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University Shihezi Xinjiang 832003 P. R. China shengchao.yang@shzu.edu.cn.
Xi-Yu WangState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 P. R. China jsyu@chem.ecnu.edu.cn.
Shengchao YangSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University Shihezi Xinjiang 832003 P. R. China shengchao.yang@shzu.edu.cn.
Jian ZhouState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 P. R. China jsyu@chem.ecnu.edu.cn.ORCID https://orcid.org/0000-0003-0679-6735
Jin-Sheng YuState Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 P. R. China jsyu@chem.ecnu.edu.cn.ORCID https://orcid.org/0000-0002-0619-2037

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Silylboronates, as powerful and versatile reagents, have been widely used in synthetic chemistry over the past few decades, due to their ability to incorporate silicon and boron atoms into organic molecules. With the rapid development of radical chemistry, the use of silylboronates as silyl radical precursors has recently become a research focus in organic synthesis. Significant achievements have been made in the synthetic applications of silylboronates as silyl radical sources for various C-Si and C-X bond forming transformations. This review summarizes these recent advances, discusses their advantages and limitations, and illustrates the synthetic chances still open for further research and applications in this emerging area.

Identifiers

PMID39811000
PMCPMC11726062

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.