ArticleBMC chemistry2025
Adaptive alcohols-alcohols cross-coupling via TFA catalysis: access of unsymmetrical ethers.
Article in BMC chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Synthesis of Unsymmetrical Dialkyl Ethers via Direct Etherification Cocatalyzed Using FeClACS omega · 2026Article
- Covalent organic frameworks-supported copper bismuth oxide nanoparticles as an efficient and green photocatalyst for benzyl alcohol oxidation.Scientific reports · 2025Article
- Acid-promoted dehydroxylation coupling of aryl alcohols with 1,3-dicarbonyls and sulfonamides.BMC chemistry · 2025Article
- Functionalization of Electron-Rich Secondary Benzyl Alcohols in HFIP: From Thioethers to Trisubstituted Methanes.The Journal of organic chemistry · 2025Article
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Authors and funding
5 authors.
Funding
Abstract
Ethers are high value organic compounds widely applied in chemical industry, natural products, material, pharmaceuticals, argochemicals, as well as modern organic synthesis. Herein, we report an adaptive TFA-catalyzed cross-coupling of alcohols with various oxygen nucleophiles (nitro-, halogen-, sulfur-, nitrogen-, aryl-, and alkynyl-substituted aliphatic alcohols), delivering diverse unsymmetrical ethers under mild conditions and simple operation. This protocol features a broad range of substrate scope and high catalytic efficiency (54 examples, up to 99% yield). The decagram scale performance and one-step synthesis of drug molecules evidenced the potential industrial production and practicability of this protocol.
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