Near-Infrared Responsive Composites of Poly-3,4-Ethylenedioxythiophene with Fullerene Derivatives.

Oxana Gribkova, Varvara Kabanova, Ildar Sayarov, Alexander Nekrasov, Alexey Tameev

Abstract read

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Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

5 authors.

Oxana GribkovaA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Leninskii Prospect 31, Moscow 119071, Russia.

Varvara KabanovaA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Leninskii Prospect 31, Moscow 119071, Russia.

Ildar SayarovA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Leninskii Prospect 31, Moscow 119071, Russia.

Alexander NekrasovA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Leninskii Prospect 31, Moscow 119071, Russia.ORCID 0000-0001-9710-9894

Alexey TameevA.N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Leninskii Prospect 31, Moscow 119071, Russia.ORCID 0000-0001-8865-3361

Funding

Ministry of Science and Higher Education of Russia 122011300052-1Russian Science Foundation 23-19-00884

6 · The paper itself

Abstract

Electrochemical polymerization of 3,4-ethylenedioxythiophene in the presence of water-soluble fullerene derivatives was investigated. The electronic structure, morphology, spectroelectrochemical, electrochemical properties and near-IR photoconductivity of composite films of poly(3,4-ethylenedioxythiophene) with fullerenes were studied for the first time. It was shown that fullerene with hydroxyl groups creates favorable conditions for the formation of PEDOT chains and more effectively compensates for the positive charges on the PEDOT chains. The near-IR photoconductivity results from the generation of charge carriers due to electron transfer from the photoexcited PEDOT molecule to the fullerene acceptor.

Indexed as

electrochemical polymerizationfullerenePEDOTphotoconductivityspectroelectrochemistry

Identifiers

PMID39795418

DOI10.3390/polym17010014

PMCPMC11723435

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