Synthesis of 2-Deoxyglycosides with Exclusive β-Configuration Using 2-SAc Glycosyl Bromide Donors.

Yang-Fan Guo, Tian-Tian Xu, Guo-Hui Zhang, Hai Dong

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

4 authors.

Yang-Fan GuoKey Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry & Chemical Engineering, Huazhong University of Science & Technology, Ministry of Education, Luoyu Road 1037, Wuhan 430074, China.

Tian-Tian XuKey Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry & Chemical Engineering, Huazhong University of Science & Technology, Ministry of Education, Luoyu Road 1037, Wuhan 430074, China.

Guo-Hui ZhangKey Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry & Chemical Engineering, Huazhong University of Science & Technology, Ministry of Education, Luoyu Road 1037, Wuhan 430074, China.

Hai DongKey Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry & Chemical Engineering, Huazhong University of Science & Technology, Ministry of Education, Luoyu Road 1037, Wuhan 430074, China.ORCID 0000-0002-9794-1805

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In this study, we developed an indirect method for the synthesis of 2-deoxyglycosides with an exclusive β-configuration using glucosyl and galactosyl bromide donors with 2-thioacetyl (SAc) groups. The 2-SAc glucosyl and galactosyl bromide donors were easily obtained through the treatment of 1-OAc, 2-SAc glucose and galactose with HBr-CH

Indexed as

2-deoxyglycosidedesulfurizationglycosylationKoenigs–Knorr conditionβ-configuration

Identifiers

PMID39795241

DOI10.3390/molecules30010185

PMCPMC11721102

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