Evidence map›Paper›PMID 39786341›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Abstraction of Hydride from Alkanes and Dihydrogen by the Perfluorotrityl Cation.

Derek W Leong, Achyut R Gogoi, Tapas Maity, Chun-I Lee, Nattamai Bhuvanesh, Osvaldo Gutierrez, Oleg V Ozerov

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Luminescent Perhalofluoro Trityl Radicals.Journal of the American Chemical Society · 2025
    Article
  2. The Pentafluorophenyl Cation: A Superelectrophile and Diradical.Angewandte Chemie (International ed. in English) · 2025
    Article
  3. Abstraction of Hydride from Alkanes and Dihydrogen by the Perfluorotrityl Cation.Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Derek W LeongDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.
Achyut R GogoiDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.
Tapas MaityDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.
Chun-I LeeDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.
Nattamai BhuvaneshDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.
Osvaldo GutierrezDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.
Oleg V OzerovDepartment of Chemistry, Texas A&M University, TAMU - 3255, College Station, Texas, USA, 77842.ORCID https://orcid.org/0000-0002-5627-1120

Funding

New Directions in Sustainable Open-Shell Radical C-C Bond Formations Enabled by Merging Modern Computational and Experimental MethodsR35GM137797 · NIGMS · UNIV OF MARYLAND, COLLEGE PARK · PI Osvaldo Gutierrez · 2020 to 2026
$2.7M
Basic Energy Sciences DE-SC0023280NIGMS NIH HHS R35 GM137797NIGMS NIH HHS R35GM137797
6 · The paper itself

Abstract

Lewis acids play a central role in a large variety of chemical transformations. The reactivity of the strongest Lewis acids is typically studied in the context of affinity towards hard bases, such as fluoride or oxygenous species. Carbocations can be viewed as soft Lewis acids, possessing significant affinity for softer bases, such as hydride. This work presents the ambient-temperature isolation of salts of the perfluorotrityl cation ((C

Indexed as

CarbocationCarboraneHydride abstractionSilylium

Identifiers

PMID39786341
PMCPMC11976196

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.