Evidence map›Paper›PMID 39781222›Full record

ArticleChemical science2025

Metathesis chemistry of inorganic cumulenes driven by B-O bond formation.

Jianqin Tang, Chenyang Hu, Agamemnon E Crumpton, Liam P Griffin, Jose M Goicoechea, Simon Aldridge

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Jianqin TangInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford South Parks Road Oxford OX1 3QR UK simon.aldridge@chem.ox.ac.uk.
Chenyang HuInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford South Parks Road Oxford OX1 3QR UK simon.aldridge@chem.ox.ac.uk.
Agamemnon E CrumptonInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford South Parks Road Oxford OX1 3QR UK simon.aldridge@chem.ox.ac.uk.
Liam P GriffinInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford South Parks Road Oxford OX1 3QR UK simon.aldridge@chem.ox.ac.uk.
Jose M GoicoecheaDepartment of Chemistry, Indiana University 800 E. Kirkwood Ave Bloomington IN 47405 USA jgoicoec@iu.edu.ORCID https://orcid.org/0000-0002-7311-1663
Simon AldridgeInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford South Parks Road Oxford OX1 3QR UK simon.aldridge@chem.ox.ac.uk.ORCID https://orcid.org/0000-0001-9998-9434

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The reaction chemistry of an unprecedented 'inorganic cumulene' - featuring a five-atom BNBNB chain - towards C[double bond, length as m-dash]O (and related) multiple bonds is disclosed. In marked contrast to related all-carbon systems, the intrinsic polarity of the BNBNB chain (featuring electron-rich nitrogen and electron-deficient boron centres) enables metathesis chemistry with electrophilic heteroallenes such as CO

Identifiers

PMID39781222
PMCPMC11706233

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.