ArticleThe journal of physical chemistry letters2025
Charge Transfer-Induced Weakening of Vibronic Coupling for Single Terrylene Molecules Adsorbed onto Hexagonal Boron Nitride.
Article in The journal of physical chemistry letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Emission dipole orientation reveals dynamic single-molecule interactions with 2D crystals at solvent interfaces.Nature communications · 2026Article
- Modulation of Single-Molecule Emission at Hexagonal Boron Nitride Surfaces.Nano letters · 2026Article
- Systematic investigation of the generation of luminescent emitters in hBN via irradiation engineering.Scientific reports · 2025Article
- Plasma-Tunable Metasurfaces for SERS Nanosensing of Hazardous Chemicals.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
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Authors and funding
8 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Fluorescence spectra of single terrylene molecules adsorbed on hexagonal boron nitride flakes were recorded at cryogenic temperatures. The pure electronic transitions of terrylene molecules are spread over a broad energy scale from 570 to 610 nm. Surprisingly, peaks in the vibrationally resolved fluorescence spectrum show intensity variations of ≤20-fold between molecules. We find an extreme case in which the Debye-Waller-Franck-Condon factor of the zero-phonon line exceeds 0.8. The vibronic intensity correlates with both the spectral position of the electronic transition and the frequency of the longitudinal stretch mode, which varies between 243 and 257 cm
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