ArticleJournal of the American Chemical Society2025
A Spectrochemical Series for Electron Spin Relaxation.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
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Who cites it
9 citing papers in PubMed.
- Excited-state orbital angular momentum enables all-optical molecular spin coherence.Chemical science · 2026Article
- Molecular Qubits for Anion Sensing by Tuning Electron Spin Relaxation via Axial Ligand Field.Angewandte Chemie (International ed. in English) · 2026Article
- Quantum coherence enhancement through control of metal-ligand covalency: modulating spin-orbit coupling in isostructural molecular qubits.Chemical science · 2026Article
- Orientationally Resolved Electron-Spin Relaxation and Coherence in Fullerene-Encapsulated Rare-Earth Dimers with a Single-Electron Metal-Metal Bond.Journal of the American Chemical Society · 2026Article
- Bridging Vibrations and Spins: Mode-Resolved Spin-Phonon Coupling Revealed through THz EPR/Magnetic IR Simulation.The journal of physical chemistry. A · 2026Article
- A Multireference Picture of Electronic Excited States in Vanadyl and Copper Tetraphenyl Porphyrin Molecular Qubits.The journal of physical chemistry. A · 2025Article
- Bridging Between Japan-Originated Inorganic Chemistry Theories and the Latest DFT Calculations.Molecules (Basel, Switzerland) · 2025Article
- Molecular Design for Optically Induced Magnetization: Targeting Excited State Orbital Degeneracy in Tungsten(V) Complexes.Journal of the American Chemical Society · 2025Article
- Slow Electron Spin Relaxation at Ambient Temperatures with Copper Coordinated by a Rigid Macrocyclic Ligand.Journal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Controlling the rate of electron spin relaxation in paramagnetic molecules is essential for contemporary applications in molecular magnetism and quantum information science. However, the physical mechanisms of spin relaxation remain incompletely understood, and new spectroscopic observables play an important role in evaluating spin dynamics mechanisms and structure-property relationships. Here, we use cryogenic magnetic circular dichroism (MCD) spectroscopy and pulse electron paramagnetic resonance (EPR) in tandem to examine the impact of ligand field (d-d) excited states on spin relaxation rates. We employ a broad scope of square-planar Cu(II) compounds with varying ligand field strength, including CuS
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.