ArticlePolymers2024
Investigation of Solid-State Thermal Decomposition of Ammonia Borane Mix with Sulphonated Poly(ellagic Acid) for Hydrogen Release.
Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Tuning the Solid-State Hydrogen Release of Ammonia Borane by Entrapping the Intermediates: The Role of High-Boiling-Point Amines.Molecules (Basel, Switzerland) · 2025Article
- Deep Eutectic Solvents Formed by Complex Hydrides: A New Class of Hydrogen-Rich Liquid.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Synthesis, Structural Characterization, and Hydrogen Release of Al-Based Amidoboranes Derived from MAlHMolecules (Basel, Switzerland) · 2025Article
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The utilization of hydrogen in safety conditions is crucial for the development of a hydrogen-based economy. Among all methodologies, solid-state hydrogen release from ammonia borane through thermal stimuli is very promising due to the high theoretical hydrogen release. Generally, carbonaceous or inorganic matrices have been used to tune the reactivity of ammonia borane. Nevertheless, these solutions lack chemical tunability, and they do not allow one to properly tune the complex chemical pathway of hydrogen release from ammonia borane. In this study, we investigated the effect of a bioderived multifunctional polymeric matrix on hydrogen release from ammonia borane, reaching pure hydrogen release of 1.2 wt.% at 94 °C. We also describe new chemical pathways involving the formation of anchored intermediates, namely BxNy species.
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