Evidence map›Paper›PMID 39771321›Full record

ArticlePolymers2024

Novel Nanocomposites and Biopolymer-Based Nanocomposites for Hexavalent Chromium Removal from Aqueous Media.

Adina-Elena Segneanu, Ionela Amalia Bradu, Mihaela Simona Calinescu Bocanici, Gabriela Vlase, Titus Vlase, Daniel-Dumitru Herea, Gabriela Buema, Maria Mihailescu, Ioan Grozescu

Abstract read
In one paragraph

Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Biogenic FeMolecules (Basel, Switzerland) · 2026
    Article
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  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Adina-Elena SegneanuInstitute for Advanced Environmental Research, West University of Timisoara (ICAM-WUT), 4 Oituz St., 300086 Timișoara, Romania.ORCID 0000-0002-1623-8094
Ionela Amalia BraduInstitute for Advanced Environmental Research, West University of Timisoara (ICAM-WUT), 4 Oituz St., 300086 Timișoara, Romania.ORCID 0009-0005-8738-3642
Mihaela Simona Calinescu BocaniciFaculty of Chemistry, Biology, Geography, West University of Timisoara (ICAM-WUT), Pestalozzi St. 16, 300115 Timișoara, Romania.
Gabriela VlaseInstitute for Advanced Environmental Research, West University of Timisoara (ICAM-WUT), 4 Oituz St., 300086 Timișoara, Romania.ORCID 0000-0002-1307-7010
Titus VlaseInstitute for Advanced Environmental Research, West University of Timisoara (ICAM-WUT), 4 Oituz St., 300086 Timișoara, Romania.ORCID 0000-0002-7480-7486
Daniel-Dumitru HereaNational Institute of Research and Development for Technical Physics, 47 Mangeron Blvd, 700050 Iasi, Romania.ORCID 0000-0002-8455-8380
Gabriela BuemaNational Institute of Research and Development for Technical Physics, 47 Mangeron Blvd, 700050 Iasi, Romania.
Maria MihailescuDepartment of Applied Chemistry and Engineering of Inorganic Compounds and the Environment, University Politehnica Timisoara, 2 Piata Victoriei, 300006 Timișoara, Romania.
Ioan GrozescuDepartment of Applied Chemistry and Engineering of Inorganic Compounds and the Environment, University Politehnica Timisoara, 2 Piata Victoriei, 300006 Timișoara, Romania.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Designing new engineered materials derived from waste is essential for effective environmental remediation and reducing anthropogenic pollution in our economy. This study introduces an innovative method for remediating metal-contaminated water, using two distinct waste types: one biowaste (eggshell) and one industrial waste (fly ash). We synthesized three novel, cost-effective nanoadsorbent types, including two new tertiary composites and two biopolymer-based composites (specifically k-carrageenan and chitosan), which targeted chromium removal from aqueous solutions. SEM analysis reveals that in the first composite, EMZ, zeolite, and magnetite nanoparticles are successfully integrated into the porous structure of the eggshell. In the second composite (FMZ), fly ash and magnetite particles are similarly loaded within the zeolite pores. Each biopolymer-based composite is derived by incorporating the corresponding tertiary composite (FMZ or EMZ) into the biopolymer framework. Structural modifications of the eggshell, zeolite, chitosan, and k-carrageenan resulted in notable increases in specific surface area, as confirmed by BET analysis. These enhancements significantly improve chromium adsorption efficiency for each adsorbent type developed. The adsorption performances achieved are as follows: EMZ (89.76%), FMZ (84.83%), EMZCa (96.64%), FMZCa (94.87%), EMZC (99.64%), and FMZC (97.67%). The findings indicate that chromium adsorption across all adsorbent types occurs via a multimolecular layer mechanism, which is characterized as spontaneous and endothermic. Desorption studies further demonstrate the high reusability of these nanomaterials. Overall, this research underscores the potential of utilizing waste materials for new performant engineered low-cost composites and biocomposites for environmental bioremediation applications.

Indexed as

adsorbentbiopolymer-based compositeheavy metal pollutionwasteswater remediation

Identifiers

PMID39771321
PMCPMC11728716

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.