ArticleMolecules (Basel, Switzerland)2024
Adsorption and Removal of 2,4,6-Trinitrotoluene by a Glycoluril-Derived Molecular-Clip-Based Supramolecular Organic Framework.
Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A glycoluril-derived molecular-clip-based supramolecular organic framework (clip-SOF) with intrinsic porosity was prepared. The clip-SOF was used for the adsorption and removal of 2,4,6-trinitrotoluene (TNT) driven by noncovalent interactions. The efficiency of TNT removal by clip-SOFs is up to 88.5% in adsorption equilibrium, and the TNT adsorption capacity of clip-SOFs is about 40.2 mg/g at 25.0 °C. Clip-SOFs have good reusability, exhibiting almost no loss in performance in ten consecutive recycling tests. This work not only provides a new method for adsorbing energetic materials, but also promotes the application of supramolecular hosts in crystal engineering.
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