Impact of Water Purity and Oxygen Content in Gas Phase on Effectiveness of Surface Cleaning with Microbubbles.

Cleaning of surfaces without complex cleaning agents is an important subject, especially in food, pharmaceutical, and biomedical applications. The subject of microbubble and nanobubble cleaning is considered one of the most promising ways to intensify this process. In this work, we check whether and how the purity of water used for microbubble generation, as well as the gas used, affects the effectiveness of cleaning stainless-steel surfaces. Surfaces contaminated with Pluronic L-121 solution were cleaned by water of three purities: ultrapure water (<0.05 μS/cm), water after reversed osmosis (~6.0 μS/cm), and tap water (~0.8 mS/cm). Similarly, three different gases were supplied to the generation setup for microbubble generation: air, oxygen, and nitrogen. Stainless steel plates were immersed in water during microbubble generation and cleaned for a given time. FTIR (Fourier Transform Infrared Spectroscopy) and contact angle analysis were employed for the analysis of surfaces. The results of cleaning were repeatable between plates and showed different cleaning effects depending on both the purity of water (concentration of ions) and gas composition. We have proposed different mechanisms that are dominant with respect to specific combinations of ion concentration and oxygen content in gas, which are directly connected to the microbubble stability and reactivity of gas.