ArticleEntropy (Basel, Switzerland)2024
Revisions of the Phenomenological and Statistical Statements of the Second Law of Thermodynamics.
Article in Entropy (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The status of the Second Law of Thermodynamics, even in the 21st century, is not as certain as when Arthur Eddington wrote about it a hundred years ago. It is not only about the truth of this law, but rather about its strict and exhaustive formulation. In the previous article, it was shown that two of the three most famous thermodynamic formulations of the Second Law of Thermodynamics are non-exhaustive. However, the status of the statistical approach, contrary to common and unfounded opinions, is even more difficult. It is known that Boltzmann did not manage to completely and correctly derive the Second Law of Thermodynamics from statistical mechanics, even though he probably did everything he could in this regard. In particular, he introduced molecular chaos into the extension of the Liouville equation, obtaining the Boltzmann equation. By using the
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