Evidence map›Paper›PMID 39762625›Full record

ArticleNature chemistry2025

Uniform single-crystal mesoporous metal-organic frameworks.

Zirui Lv, Runfeng Lin, Yi Yang, Kun Lan, Chin-Te Hung, Pengfei Zhang, Jinxiu Wang, Wanhai Zhou, Zaiwang Zhao, Zhongyao Wang and 10 more

Abstract read
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Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

20 authors.

Zirui LvLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0009-0006-4738-7339
Runfeng LinLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.
Yi YangLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.
Kun LanCollege of Energy Materials and Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, P. R. China.
Chin-Te HungLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.
Pengfei ZhangCollege of Energy Materials and Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, P. R. China.
Jinxiu WangLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.
Wanhai ZhouLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0003-3197-9971
Zaiwang ZhaoCollege of Energy Materials and Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, P. R. China.ORCID http://orcid.org/0000-0002-1874-2518
Zhongyao WangSchool of Computer Science, Shanghai Key Laboratory of Intelligent Information Processing, Fudan University, Shanghai, P. R. China.
Jiawen ZouSchool of Computer Science, Shanghai Key Laboratory of Intelligent Information Processing, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0009-0002-4357-0292
Taoyang WangSchool of Computer Science, Shanghai Key Laboratory of Intelligent Information Processing, Fudan University, Shanghai, P. R. China.
Tiancong ZhaoLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0003-1995-2274
Yifei XuLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0001-5180-8892
Dongliang ChaoLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0001-7793-0044
Weimin TanSchool of Computer Science, Shanghai Key Laboratory of Intelligent Information Processing, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0001-7677-4772
Bo YanSchool of Computer Science, Shanghai Key Laboratory of Intelligent Information Processing, Fudan University, Shanghai, P. R. China.
Qiaowei LiLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0002-5987-9465
Dongyuan ZhaoLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China.ORCID http://orcid.org/0000-0001-8440-6902
Xiaomin LiLaboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM), College of Chemistry and Materials, Fudan University, Shanghai, P. R. China. lixm@fudan.edu.cn.ORCID http://orcid.org/0000-0001-6056-6928

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22075049National Natural Science Foundation of China (National Science Foundation of China) 22088101National Natural Science Foundation of China (National Science Foundation of China) 22205038National Natural Science Foundation of China (National Science Foundation of China) 22305042National Natural Science Foundation of China (National Science Foundation of China) 61902076National Natural Science Foundation of China (National Science Foundation of China) U2001209
6 · The paper itself

Abstract

The synthesis of mesoporous metal-organic frameworks (meso-MOFs) is desirable as these materials can be used in various applications. However, owing to the imbalance in structural tension at the micro-scale (MOF crystallization) and the meso-scales (assembly of micelles with MOF subunits), the formation of single-crystal meso-MOFs is challenging. Here we report the preparation of uniform single-crystal meso-MOF nanoparticles with ordered mesopore channels in microporous frameworks with definite arrangements, through a cooperative assembly method co-mediated by strong and weak acids. These nanoparticles feature a truncated octahedron shape with variable size and well-defined two-dimensional hexagonally structured (p6mm) columnar mesopores. Notably, the match between the crystallization kinetics of MOFs and the assembly kinetics of micelles is critical for forming the single-crystal meso-MOFs. On the basis of this strategy, we have constructed a library of meso-MOFs with tunable large pore sizes, controllable mesophases, various morphologies and multivariate components.

Identifiers

PMID39762625

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