ArticleSmall (Weinheim an der Bergstrasse, Germany)2025
Asymmetric Microgels with Tunable Morphologies by Assembly-Guided Polymerization of Liquid Crystalline Monomers.
Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Thermoresponsive Copolymer Microgels Synthesized via Single-Step Precipitation Polymerization: Random or Block Structure?Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Asymmetric Microgels with Tunable Morphologies by Assembly-Guided Polymerization of Liquid Crystalline Monomers.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Understanding and controlling the morphology of microgels is crucial for optimizing their properties and functions in diverse areas of application. The fabrication of microgels that exhibit both structural and chemical anisotropy using a template-free approach faces significant challenges. Existing approaches toward such microgels are typically limited to templating methods with low throughput. Here, an alternative bottom-up approach is developed for producing non-spherical N-vinylcaprolactam (VCL) based microgels through semi-batch precipitation polymerization, incorporating a functional comonomer with a liquid crystalline (LC) moiety. 4-methoxybenzoic acid 4-(6-acryloyloxy-hexyloxy)phenyl ester (LCM) is used as the LC comonomer. The resulting morphology of those microgels is tuned to multilobe-, dumbbell-, and raspberry-like shapes. The different morphologies are obtained by varying the addition time of LCM, temperature, solvent ratio, and monomer ratio. The microgel morphologies are characterized by (cryogenic) transmission and scanning electron microscopy. The thermoresponsiveness is investigated by dynamic light scattering (DLS), while the incorporation of LCM into the microgel structure is determined via
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