Evidence map›Paper›PMID 39753512›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Carbon-Centered Reactivity in Carbodiphosphorane-Based Ligands Allowing for Redox-Non-Innocent Ligand/Ligand Dual Bond-Activation.

Philipp Schatz, Weiqin Xu, Sebastian Rynek, Leon Maser, Niels Heise, Olaf Fuhr, Dieter Fenske, Haleh Hashemi Haeri, Dariush Hinderberger, Matthias Vogt and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Philipp SchatzInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.
Weiqin XuChemistry Department, Guangdong University of Education, Guangzhou, 510303, PR China.
Sebastian RynekInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.
Leon MaserInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.
Niels HeiseInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.ORCID https://orcid.org/0000-0002-6540-6357
Olaf FuhrInstitut für Nanotechnologie (INT) and Karlsruhe Nano Micro Facility (KNMFi), Karlsruher Institut für Technologie (KIT), Kaiserstraße 12, 76131, Karlsruhe, Germany.
Dieter FenskeInstitut für Nanotechnologie (INT) and Karlsruhe Nano Micro Facility (KNMFi), Karlsruher Institut für Technologie (KIT), Kaiserstraße 12, 76131, Karlsruhe, Germany.
Haleh Hashemi HaeriInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.
Dariush HinderbergerInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.ORCID https://orcid.org/0000-0002-6066-7099
Matthias VogtInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.ORCID https://orcid.org/0000-0002-2636-2531
Robert LangerInstitute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.ORCID https://orcid.org/0000-0001-5746-9940

Funding

Deutsche Forschungsgemeinschaft LA 2830/6-2Deutsche Forschungsgemeinschaft LA 2830/9-1
6 · The paper itself

Abstract

A pronounced nucleophilicity in combination with a distinct redox non-innocence is a unique feature of a coordinated ligand, which in the current case, leads to unprecedented carbon-centered reactivity patterns: A carbodiphosphorane-based (CDP) pincer-type rhodium complex allows to cleave two C-Cl-bonds of geminal dichlorides via two consecutive S.

Indexed as

carbodiphosphoraneshomogeneous catalysisligand reactivitymetal-ligand-cooperationredox noninnocence

Identifiers

PMID39753512
PMCPMC11811687

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.