Evidence map›Paper›PMID 39747237›Full record

ArticleNature communications2025

2.5-dimensional covalent organic frameworks.

Tomoki Kitano, Syunto Goto, Xiaohan Wang, Takayuki Kamihara, Yoshihisa Sei, Yukihito Kondo, Takumi Sannomiya, Hidehiro Uekusa, Yoichi Murakami

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Tomoki KitanoLaboratory for Zero-Carbon Energy, Institute of Integrated Research, Institute of Science Tokyo, Tokyo, Japan.ORCID http://orcid.org/0009-0002-9373-3715
Syunto GotoLaboratory for Zero-Carbon Energy, Institute of Integrated Research, Institute of Science Tokyo, Tokyo, Japan.ORCID http://orcid.org/0009-0009-7811-9152
Xiaohan WangLaboratory for Zero-Carbon Energy, Institute of Integrated Research, Institute of Science Tokyo, Tokyo, Japan.
Takayuki KamiharaFacility Station Division, Open Facility Center, Institute of Science Tokyo, Yokohama, Japan.ORCID http://orcid.org/0000-0002-6519-7399
Yoshihisa SeiFacility Station Division, Open Facility Center, Institute of Science Tokyo, Yokohama, Japan.ORCID http://orcid.org/0000-0002-8321-3620
Yukihito KondoDepartment of Materials Science & Engineering, Institute of Science Tokyo, Yokohama, Japan.
Takumi SannomiyaDepartment of Materials Science & Engineering, Institute of Science Tokyo, Yokohama, Japan.ORCID http://orcid.org/0000-0001-7079-2937
Hidehiro UekusaDepartment of Chemistry, Institute of Science Tokyo, Tokyo, Japan.ORCID http://orcid.org/0000-0001-9809-1411
Yoichi MurakamiLaboratory for Zero-Carbon Energy, Institute of Integrated Research, Institute of Science Tokyo, Tokyo, Japan. murakami.y.af@m.titech.ac.jp.ORCID http://orcid.org/0000-0001-9536-1631

Funding

MEXT | Japan Society for the Promotion of Science (JSPS) JP22H05033MEXT | Japan Society for the Promotion of Science (JSPS) JP22K18286MEXT | Japan Society for the Promotion of Science (JSPS) JP23H00165MEXT | Japan Society for the Promotion of Science (JSPS) JP24H00005
6 · The paper itself

Abstract

Covalently bonded crystalline substances with micropores have broad applications. Covalent organic frameworks (COFs) are representative of such substances. They have so far been classified into two-dimensional (2D) and three-dimensional (3D) COFs. 2D-COFs have planar shapes useful for broad purposes, but obtaining good crystals of 2D-COFs with sizes larger than 10 μm is significantly challenging, whereas yielding 3D-COFs with high crystallinity and larger sizes is easier. Here, we show COFs with 2.5-dimensional (2.5D) skeletons, which are microscopically constructed with 3D bonds but have macroscopically 2D planar shapes. The 2.5D-COFs shown herein achieve large single-crystal sizes above 0.1 mm and ultrahigh-density primary amines regularly allocated on and pointing perpendicular to the covalently-bonded network plane. Owing to the latter nature, the COFs are promising as CO

Identifiers

PMID39747237
PMCPMC11696810

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.