ArticleAngewandte Chemie (International ed. in English)2025
Photocatalytic Dehalogenation of Aryl Halides Mediated by the Flexible Metal-Organic Framework MIL-53(Cr).
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Quasi-Closed-Loop Crystal-Amorphous Solid-Wet Gel Transformation in Copper MOFs for Exceptional Cycling Stability in Cascade Reactions.Angewandte Chemie (International ed. in English) · 2026Article
- Leveraging Conformational Dynamics of MOFs to Overcome Conversion-Selectivity Trade-Off in COAngewandte Chemie (International ed. in English) · 2026Article
- In Situ Insights into Enhanced Cooperative Ligand Exchange Kinetics via Solvent-Induced Restacking in a 2D Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- Photocatalytic Dehalogenation of Aryl Halides Mediated by the Flexible Metal-Organic Framework MIL-53(Cr).Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
12 authors.
Funding
Abstract
The catalytic potential of flexible metal-organic frameworks (MOFs) remains underexplored, particularly in liquid-phase reactions. This study employs MIL-53(Cr), a prototypical "breathing" MOF capable of structural adaptation via pore size modulation, as a photocatalyst for the dehalogenation of aryl halides. Powder X-ray diffraction and Pair Distribution Function analyses reveal that organic solvents influence pore opening, while substrates and products dynamically adjust the framework configuration during catalysis. This structural flexibility enables precise tuning of photocatalytic efficiency via solvent-mediated control of the pore aperture. The results demonstrate that the dynamic behavior of MIL-53(Cr) facilitates enhanced catalytic activity and selectivity, advancing the application of flexible MOFs as tunable, enzyme-mimicking catalysts. These findings pave the way for the rational design of next-generation flexible photocatalysts.
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