ArticleACS omega2024
Phloroglucinol-Based Antimicrobial Shape-Memory Photopolymers for Microimprint Lithography.
Article in ACS omega, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
6 authors.
Funding
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Abstract
In this study, for the first time, biobased photopolymers were synthesized from phloroglucinol tris epoxy with and without different comonomers, phloroglucinol, 1,4:3,6-dianhydro-D-sorbitol, and 1,4-cyclohexanedimethanol. The rheological, thermal, mechanical, shape-memory, and antimicrobial properties of photopolymers were investigated. The addition of comonomers reduced the photocuring rate (gel time increased from 325 s to 434-861 s) and rigidity (storage modulus decreased from 330.76 to 15.42-85.77 MPa), reduced their brittleness, and increased the flexibility (elongation at break increased from 0.9 to 1.89-4.51%), although the tensile strength of the polymers remained sufficiently high (tensile strength was reduced from 292.00 to 132.62-234.54 MPa). All polymers exhibited a thermoresponsive shape-memory behavior as they could maintain a temporary shape below their glass-transition temperature and return to the permanent shape when the temperature was raised again above the glass-transition temperature. All polymers showed high antibacterial activity against
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Registered trials
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