Evidence map›Paper›PMID 39737917›Full record

ArticleNature communications2024

Understanding water reaction pathways to control the hydrolytic reactivity of a Zn metal-organic framework.

Shoushun Chen, Zelin Zhang, Wei Chen, Bryan E G Lucier, Mansheng Chen, Wanli Zhang, Haihong Zhu, Ivan Hung, Anmin Zheng, Zhehong Gan and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Shoushun Chen *Lanzhou Magnetic Resonance Center, Frontiers Science Center for Rare Isotopes, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China. chenss@lzu.edu.cn.ORCID http://orcid.org/0009-0009-4315-015X
Zelin Zhang *School of Physical Science and Technology, Electron Microscopy Centre of Lanzhou University, Lanzhou University, Lanzhou, 730000, China.
Wei Chen *Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, 430071, China.ORCID http://orcid.org/0000-0002-8955-9497
Bryan E G LucierDepartment of Chemistry, University of Western Ontario, London, Ontario, N6A 5B7, Canada.ORCID http://orcid.org/0000-0002-9682-4324
Mansheng ChenDepartment of Chemistry, University of Western Ontario, London, Ontario, N6A 5B7, Canada.
Wanli ZhangDepartment of Chemistry, University of Western Ontario, London, Ontario, N6A 5B7, Canada.
Haihong ZhuLanzhou Magnetic Resonance Center, Frontiers Science Center for Rare Isotopes, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China.
Ivan HungNational High Magnetic Field Laboratory (NHMFL), 1800 East Paul Dirac Dr, Tallahassee, Florida, 32310, USA.ORCID http://orcid.org/0000-0001-8916-739X
Anmin ZhengInnovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, 430071, China.ORCID http://orcid.org/0000-0001-7115-6510
Zhehong GanNational High Magnetic Field Laboratory (NHMFL), 1800 East Paul Dirac Dr, Tallahassee, Florida, 32310, USA.
Dongsheng LeiSchool of Physical Science and Technology, Electron Microscopy Centre of Lanzhou University, Lanzhou University, Lanzhou, 730000, China. leids@lzu.edu.cn.ORCID http://orcid.org/0000-0003-1640-0693
Yining HuangDepartment of Chemistry, University of Western Ontario, London, Ontario, N6A 5B7, Canada. yhuang@uwo.ca.ORCID http://orcid.org/0000-0001-9265-5896

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22105091National Natural Science Foundation of China (National Science Foundation of China) 32171300National Science Foundation (NSF) DMR-2128556
6 · The paper itself

Abstract

Metal-organic frameworks (MOFs) are a class of porous materials that are of topical interest for their utility in water-related applications. Nevertheless, molecular-level insight into water-MOF interactions and MOF hydrolytic reactivity remains understudied. Herein, we report two hydrolytic pathways leading to either structural stability or framework decomposition of a MOF (ZnMOF-1). The two distinct ZnMOF-1 water reaction pathways are linked to the diffusion rate of incorporated guest dimethylformamide (DMF) molecules: slow diffusion of DMF triggers evolution of the initial MOF into a water-stable MOF product exhibiting enhanced water adsorption, while fast exchange of DMF with water leads to decomposition. The starting MOF, three intermediates from the water reaction pathways and the final stable MOF have been characterized. The documentation of two distinct pathways counters the stereotype that water exposure always leads to destruction or degradation of water-sensitive MOFs, and demonstrates that water-stable MOFs with improved adsorption properties can be prepared via controlled solvent-triggered structural rearrangement.

Identifiers

PMID39737917
PMCPMC11685767

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