Evidence map›Paper›PMID 39735819›Full record

ArticleChem catalysis2024

Visible Light-Driven Excited-State Copper-BINAP Catalysis for Accessing Diverse Chemical Reactions.

Upasana Mukherjee, Jagrut A Shah, Ming-Yu Ngai

Abstract read
In one paragraph

Article in Chem catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Upasana MukherjeeDepartment of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
Jagrut A ShahDepartment of Chemistry, State University of New York, Stony Brook, New York 11794, United States.
Ming-Yu NgaiDepartment of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.

Funding

Novel Strategies and Reagents for Introduction of Fluorinated GroupsR35GM119652 · NIGMS · STATE UNIVERSITY NEW YORK STONY BROOK · PI Ming-Yu Ngai · 2016 to 2026
$4.8M
NIGMS NIH HHS R35 GM119652
6 · The paper itself

Abstract

The use of visible light to drive chemical transformations has a history spanning over a century. However, the development of photo-redox catalysts to efficiently harness light energy is a more recent advancement, evolving over the past two decades. While ruthenium and iridium-based photocatalysts dominate due to their photostability, long excited-state lifetimes, and high redox potentials, concerns about sustainability and cost have shifted attention to first-row transition metals. Luminescent Cu(I) complexes have emerged as promising alternatives, offering open-shell reactivity and tunable photoelectrochemical properties. This review (i) provides an overview of the structural, photophysical, and electrochemical properties governing copper(I) complexes; (ii) highlights advances in Cu(I)-BINAP catalysis for carbon-carbon and carbon-heteroatom bond formations under mild conditions; and (iii) analyzes the trajectory of this catalytic system, addressing challenges and identifying opportunities for further development.

Identifiers

PMID39735819
PMCPMC11671124

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.